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Adult
shoot
with
backless
dress
in
capital
city
(3,5)
Adult shoot with backless dress in capital city (3,5)
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How the clue works
The definition is capital city, and the rest builds it piece by piece. Start with A (adult), then add BUD (shoot), and finish with HABI, which is HABIT (dress) with its last letter dropped, as 'backless' tells you. String them together and you get the capital.