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Imposing
women
arrange
bets
(8)
Imposing women arrange bets (8)
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The definition is at the beginning of the clue.
How the clue works
See Imposing women at the front — that's your definition, pointing to dowagers, those dignified old dames of high social standing. For the wordplay, DO gives you "arrange", and WAGERS gives you "bets", stick them together and you've got it.