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Principally,
social
categorisation
has
one
overwhelming
limitation
–
it’s
divided
by
class
(6)
Principally, social categorisation has one overwhelming limitation – it’s divided by class (6)
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The definition is at the end of the clue.
How the clue works
Right, see "Principally" sitting there — that's your nudge to just take the first letters of the run of words. So Social, Categorisation, Has, One, Overwhelming, Limitation give you S-C-H-O-O-L. And the definition's tucked at the end, "it's divided by class" — a school being the thing organised into classes, which is exactly what you've built.