24 across
Focused
on
getting
money
–
shamefaced
(7)
Focused on getting money – shamefaced (7)
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The definition is at the beginning of the clue.
How the clue works
Right, so "Focused" is your definition — that's just CENTRED, meaning concentrated on something. For the wordplay, you're building it in two chunks: CENT for "getting money" (a coin, after all), then RED for "shamefaced" — think red-faced with embarrassment — stuck together to give you CENTRED.