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Hero
knocked
over
nuclear
fuel
(4)
Hero knocked over nuclear fuel (4)
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The definition is at the beginning of the clue.
How the clue works
Right, so Hero is your definition here — a lion's a heroic sort, brave as they come. For the wordplay, take N (that's the abbreviation for nuclear) and stick it before OIL (fuel), giving you NOIL, then "knocked over" tells you to reverse it, and that flips NOIL into LION.