5 down
In
France
a
supermarket
sacking
head
to
become
international
organisation
(6)
In France a supermarket sacking head to become international organisation (6)
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The definition is at the end of the clue.
How the clue works
Right, so international organisation at the end is your definition, that's UNESCO. For the wordplay, "In France a" is telling you to translate 'a' into French, which gives UN. Then take TESCO (your supermarket) and sack its head letter, the T, leaving ESCO — stick UN in front and you've got UNESCO.