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Wild
Bunch
get
ready
to
hit
the
road
(4)
Wild Bunch get ready to hit the road (4)
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The definition is at the beginning of the clue.
How the clue works
See how the clue splits into two neat definitions here — Wild Bunch gives you PACK, like a pack of wild animals roaming about, and separately get ready to hit the road also gives PACK, as in packing your bags before you head off. Two different meanings, same word, that's your double definition sorted.