14 down
She
acts
single,
following
couple
of
males
in
certain
direction
(4,5)
She acts single, following couple of males in certain direction (4,5)
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The definition is at the beginning of the clue.
How the clue works
"She acts" is your definition, pointing to actress Emma Stone. For the wordplay, take a couple of males, MM, and stuff them inside a certain direction, EAST — that gives EMMAST — then tack on ONE for "single" to finish off EMMA STONE.