13 across
Challenger
with
gun
anticipated
getting
shot
still
(8)
Challenger with gun anticipated getting shot still (8)
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The definition is at the beginning of the clue.
How the clue works
The definition is Challenger with gun, a duellist being someone who fights duels. Start with DUE for 'anticipated', then add an anagram (signalled by 'shot') of 'still' to give LLIST, and put them together for DUELLIST.