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Emoji
used
by
wooer
in
suit
(6)
Emoji used by wooer in suit (6)
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The whole clue is the definition (& lit or double definition).
How the clue works
The definition is Emoji used by wooer — think of the heart symbol a suitor might send — and that doubles up neatly with suit, as in the card suit. The word "in" just links the two halves together.