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Actress
and
singer
also
going
up
in
smoke
(7)
Actress and singer also going up in smoke (7)
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The definition is at the end of the clue.
How the clue works
Look at smoke at the end — that's your definition, a cheroot being a type of cigar. You've got Cher, the actress and singer, then too meaning "also" gets reversed by "going up" to give OOT, and the two parts slot together nicely.