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Photo
briefly
capturing
mother,
teacher
and
a
princess
(5,5)
Photo briefly capturing mother, teacher and a princess (5,5)
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The definition is at the end of the clue.
How the clue works
The princess here refers to a spoilt, spoiled female, matching prima donna. Take PRINT for "photo" and shorten it ("briefly") to PRIN, then have it capture MA for "mother" plus DON for "teacher", giving PRIMADONN, and finish with A for "a" to complete PRIMA DONNA.