24 across
Seat
in
parliament
offered
up
for
favours
enacted,
primarily
(6)
Seat in parliament offered up for favours enacted, primarily (6)
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The definition is at the beginning of the clue.
How the clue works
Look at Seat — that's your definition, a pouffe being one of those low cushioned stools. Then "primarily" is your signal to take the first letters of parliament offered up for favours enacted, which gives you P-O-U-F-F-E.