3 down
Pianist
leaving
church
to
tour
one
part
of
Africa
(7)
Pianist leaving church to tour one part of Africa (7)
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The definition is at the end of the clue.
How the clue works
Look at part of Africa — that's your definition, the country in question. Start with LIBERACE (the flamboyant pianist), drop CE (church) to leave you with LIBERA, then slot I (one) inside it, as in "touring" through the middle, and you've got LIBER-I-A.