27 across
Mate
finally
moving
to
centre
of
mountain
range
(5)
Mate finally moving to centre of mountain range (5)
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The definition is at the end of the clue.
How the clue works
The definition is mountain range, giving you CHAIN. You've got mate as CHINA (Cockney rhyming slang), then finally moving to centre tells you to shift that last letter A into the middle, turning CHINA into CHAIN.